Search results

The susceptibility of 17‐4PH and 17‐7PH stainless steels to stress corrosion cracking (SCC) is examined in the present investigation. The specimens were tested in the presence of NaCl and NaOH (20%) at 908C and various pH values. The evaluations were carried out using the CERT test, at a speed of 10^‐6s^‐1, supplemented by anodic polarisation and electrochemical noise analysis. The main objective was to identify the conditions of both susceptibility and performance of these materials. Fractographic analyses revealed both ductile and brittle fractures. Also, the presence of intergranular cracks was a clear indication of a characteristic anodic dissolution of the material. Nevertheless, the main mechanism for stress corrosion crack propagation was hydrogen embrittlement. From the experimental results, it was concluded that electrochemical noise analysis is a reliable technique for the identification of crack nucleation and growth.

This study attempts to investigate corrosion inhibition properties of 1H-benzimidazole (B) and 1H-benzotriazole (BTA) on aluminum in 0.25 M HCl solution at different concentrations.

To this end, electrochemical techniques including electrochemical noise (EN), electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization were used.

Results showed a greater corrosion inhibition efficiency of BTA than B on aluminum in HCl solution. BTA showed greater tendency to adsorption on the metal surface than B because of the inclusion of three nitrogen atoms.

The novelty of this work is comparing EN data with EIS and potentiodynamic polarization parameters.

Existing deterministic models that predict the capacity of corroded reinforced concrete (RC) beams have limited applicability because they were based on accelerated tests that induce general corrosion. This research gap was addressed by performing a combined numerical and statistical analysis on RC beams, subjected to natural corrosion, to achieve a much better forecast.

Data of 42 naturally corroded beams were collected from the literature and analyzed numerically. Four constitutive models and their combinations were considered: the elastic-semi-plastic and elastic-perfectly-plastic models for steel, and two tensile models for concrete with and without the post-cracking stresses. Meanwhile, Popovics’ model was used to describe the behavior of concrete under compression. Corrosion coefficients were developed as functions of corrosion degree and beam parameters through linear regression analysis to fit the theoretical moment capacities with test data. The performance of the coefficients derived from different combinations of constitutive laws was then compared and validated.

The results showed that the highest accuracy (R² = 0.90) was achieved when the tensile response of concrete was modeled without the residual stresses after cracking and the steel was analyzed as an elastic-perfectly-plastic material. The proposed procedure and regression model also showed reasonable agreement with experimental data, even performing better than the current models derived from accelerated tests and traditional procedures.

This study presents a simple but reliable approach for quantifying the capacity of RC beams under more realistic conditions than previously reported. This method is simple and requires only a few variables to be employed. Civil engineers can use it to obtain a quick and rough estimate of the structural condition of corroding RC beams.

Molten sulphate-vanadate induced hot corrosion is the main reason of failure of boiler tubes used at high temperatures in thermal power plants. The hot corrosion can be encountered by applying thermal spray coatings on the alloy steels. In this perspective, this paper aims to attempt to investigate the effect of carbon nanotubes reinforcement on Cr₂O₃ composite coatings on hot corrosion behaviour of ASTM-SA213-T22 steel in a corrosive environment of Na₂SO₄ – 60%V₂O₅ at 900^°C for 50 cycles.

The coatings have been deposited with high velocity oxy fuel process. The samples were exposed to hot corrosion in a Silicon tube furnace at 900^°C for 50 cycles. The kinetics of corrosion behaviour were analysed by the weight gain measurements after each cycle. Corrosion products were analysed with X-ray diffraction, scanning electron microscopy, energy dispersive and cross-sectional analysis techniques.

During investigations, the carbon nanotubes (CNT) reinforced Cr₂O₃ composite coatings on T22 steel were found to provide better corrosion resistance in the molten salt environment at 900^°C. The coatings showed lower weight gain along with formation of protective oxide scales during the experiment. Improvement in protection against hot corrosion was observed with increase in CNT content in the coating matrix.

The addition of CNT has resulted in reduction in porosity by filling the voids in chromium oxide coating, with interlocking of particle and has blocked the penetration of corroding species to enhance the corrosion resistance of the composite coatings. The corrosion rate was found to be decreasing with increase in CNT content in coating matrix.

It must be mentioned here that high temperature corrosion behaviour of thermally sprayed CNT-Cr₂O₃ composite coatings has never been studied, and it is not available in the literature. Hence, present investigation can provide valuable information for application of CNT-reinforced coatings in high temperature fuel combustion environments.

This paper aims to study the effect of number of welding passes on microstructure, mechanical and corrosion properties of 409 M ferritic stainless steel. Shielded metal arc welding (SMAW) process is used to weld two metal sheets of 409 M having 3 mm thickness as bead-on-plate with single, double and triple passes. Microstructures were observed at transverse section with the help of optical microscope and with increasing number of passes grain growth, and the width of heat-affected zone (HAZ) increases. The results of tensile tests revealed that as number of passes increases, there is reduction in tensile strength and ductility. Double loop electrochemical potentiokinetic reactivation (DL-EPR) test revealed that as number of passes increases, the degree of sensitization increases. This is due to the deposition of chromium carbides at the grain boundaries and the associated depletion of chromium.

Three welded plates of single, double and triple pass were welded by SMAW process. From three welded plates (single, double and triple passes), samples for microstructural examination were cut in transverse direction (perpendicular to welding direction) with the help of wire-cut electrical discharge machine (EDM). The welded plates were sliced using wire-cut EDM along transverse direction for preparing optical microscopy, tensile testing, microhardness and DL-EPR testing specimens.

From the microstructure, it was observed that the large grain growth, which is dendritic, and the structure become finer to increase in number of welding passes. As number of passes increases, the width of HAZ increases because of the higher temperature at the welded zone. The tensile strength decreases to increase the number of welding passes because of grain coarsening and chromium carbide precipitation in sensitized zone and wider HAZ. The maximum microhardness value was observed for single-pass weld as compared to double- and triple-pass welds because of the fast cooling rate. The degree of sensitization increases to increase the number of passes because of chromium carbide deposition at the grain boundaries.

The authors declare that the manuscript is original and not published elsewhere, and there is no conflict of interest to publish this manuscript.

The thermal spraying technique of High-Velocity Oxygen Fuel (HVOF) coating was used to deposit coatings of an alloy composed of Ni-based substrates on stainless steel AISI 304. The aim of this study was to determine the mechanical properties such as hardness and bond strength that these coatings have when the spray distance is varied, as well as the microstructure and phases formed during the thermal spray process.

The coatings were applied by HVOF and characterized by scanning electron microscopy, image analysis, X-ray diffraction, microhardness and bond strength to analyze the mechanical properties.

The microstructure of the coatings showed low porosity, oxide content and interface contamination in the substrate–coating interface, without the presence of unmolten particles. The microhardness values reached 600 HV for the three spray distances used and the bond strength values reached over 55 MPa.

The use of coatings on aircraft components is growing dramatically owing to the high costs of advanced materials and the growing lifecycle requirements for high-performance systems, which are taken into account because of the variety of coatings and complexity of environmental factors.

The originality of this study lies in the development of new coating materials for the manufacture and protection of various turbine components. The value is based on the development of materials and processes to be used to manufacture them.

The purpose of this paper is to determine if a type of cactus mucilage, Opuntia ficus-indica (OFI), may act as a corrosion inhibitor for carbon steel in cement-based materials (mortar) exposed to chloride-laden environment.

Mortar prisms, reinforced with carbon steel rods, were immersed in sodium chloride (NaCl) solution for five wet – dry cycles. The experimentation included electrochemical monitoring (corrosion potential, Ecorr, and polarization resistance, Rp) of carbon steel during the time of exposure until corrosion-induced cracking appeared at the mortar surface. Crack survey on the mortar prisms was performed. Carbon steel rods were retrieved from the mortar after crack survey and steel mass loss at the end of the experimental period was estimated. A comparison between the different mixtures was also performed.

OFI mucilage did perform as a corrosion inhibitor of steel in chloride contaminated mortar.

The experimental program needs to be corroborated in concrete specimens with typical dimensions. The surface oxide/hydroxide formation of the carbon steel in contact with the OFI mucilage is still unknown; thus, electrochemical impedance spectroscopy (EIS) and X-ray diffraction (XRD) analyses are needed.

OFI mucilage is a suitable natural product that can be used to increase durability of concrete structures not only in countries where OFI cactus is produced, but also in many other countries where this plant is considered a plague.

The new information obtained from this paper is the innovative use of a by-product of this cactus plant for construction industry applications.